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化工学报  2015 

生物质燃油碳烟颗粒的形貌、结构与组分表征

DOI: 10.11949/j.issn.0438-1157.20140926, PP. 441-448

Keywords: 生物质燃油,碳烟颗粒,显微结构,表面,组分

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Abstract:

通过微乳化工艺分别把不同含量的精制生物质裂解油与柴油进行混合(micro-emulsifiedbiomassfuel,MEBF),研究了该类燃油碳烟颗粒的形貌与结构,并对其组分进行了表征。结果表明:该类燃油碳烟的一次颗粒形貌均为球形,而且一次颗粒之间互相连接构成链状团聚物。同时,精制生物质裂解油含量为20%(质量)(BS20)的混合油碳烟颗粒的平均粒径最小,约为32nm,其他含量混合油碳烟颗粒的平均粒径均在38nm左右。BS30石墨化程度高于其余碳烟,且BS20颗粒表面C=O和C—O—C基团含量较高,可能归因于混合油燃烧过程中复杂含氧组分的氧化程度不同。

References

[1]  Chiaramonti D, Bonini M, Fratini E. Development of emulsions from biomass pyrolysis liquid and diesel and their use in engines(Part 1): Emulsion production [J]. Biomass and Bioenergy, 2003, 25: 85-99
[2]  Park A, Kittelson D B, Zachariah M R, McMurry P H. Measurement of inherent material density of nanoparticle agglomerates [J]. Journal of Nanoparticle Research, 2004, 6:267-272
[3]  Clague A D H, Donnet J B, Wang T K, Peng J C M. A comparison of diesel engine soot with carbon black [J]. Carbon, 1999, 37(10): 1553-1565
[4]  Hu Enzhu, Hu Xianguo, Liu Tianxia, Liu Yiming, Song Ruhong, Chen Yazhou. Investigation of morphology, structure and composition of biomass-oil soot particles [J]. Applied Surface Science, 2013, 270: 596-603
[5]  Hu Enzhu, Hu Xianguo, Liu Tianxia, Fang Ling, Karl D D, Xu Hongming. The role of soot particles in the tribological behavior of engine lubricating oils [J]. Wear, 2013, 304: 152-161
[6]  Hu Enzhu, Hu Xianguo, Wang Xiangyang, Xu Yufu, Karl D D, Xu Hongming. On the fundamental lubricity of 2, 5-dimethylfuran as a synthetic engine fuel [J]. Tribology International, 2012, 55: 119-125
[7]  Liu Tianxia(刘天霞), Hu Enzhu(胡恩柱), Jin Tao(金涛), Hu Xianguo(胡献国). The composition, structure and tribological performance of soot particles from bio-fuel [J]. Tribology(摩擦学学报), 2014, 34(4): 379-386
[8]  Wang Qiongjie(王琼杰). Study of lubricity of modified bio-oil by pyrolysis liquefaction of biomass[D]. Hefei: Hefei University of Technology, 2009
[9]  Zhu Xifeng(朱锡锋), Lu Qiang(陆强), Zheng Jilu(郑冀鲁), Guo Qingxiang(郭庆祥), Zhu Qingshi(朱清时). Research on biomass pyrolysis and bio-oil characteristics [J]. Acta Energiae Solaris Sinica(太阳能学报), 2006,12: 1285-1289
[10]  Gu Shiqiang(顾世强), Wang Zhong(王忠), Mao Gongping(毛功平), Xu Guangju(许广举), Huang Huilong(黄慧龙). Analysis of factors influencing morphology of bio-diesel soot particles [J]. Environment Science and Technology(环境科学与技术), 2010,33(3): 127-130
[11]  Wei Jiaxing, Cai Meirong, Zhou Feng, Liu Weimin. Candle soot as particular additives [J]. Tribology Letters, 2014, 53(3): 521-531
[12]  Joly-Pottuza L, Matsumotoa N, Kinoshitaa H, Vacherb B, Belinb M, Montagnacc G, Martinb J M, Ohmaea N. Diamond-derived carbon onions as lubricant additives [J]. Tribology International, 2008, 41(2): 69-78
[13]  Joly-Pottuz L, Vacher B, Ohmae N, Martin J M, Epicier T. Anti-wear and friction reducing mechanisms of carbon nano-onions as lubricant additives [J]. Tribology Letters, 2008, 30(1): 69-80
[14]  Sadezky A, Poschl U, Niessner R, Grothe H, Muckenhuber H. Raman microspectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information [J].Carbon, 2005, 43(8): 1731-1742
[15]  Rzepka E, Lusson A, Ponomarev E A, Mukhopadhyay K, Sharon M, Levy-Clement C. Raman scattering investigations of semiconducting diamond-like carbon thin films and fibers obtained from camphor [J]. Carbon, 1998, 36(5): 587-590
[16]  Angoni K. Study of highly ordered carbons by use of macroscopic and microscopic Raman spectroscopy [J]. Journal of Materials Science, 1998, 33(14): 3693-3698
[17]  Li Hui(李辉), Yang Chuanzheng(杨传铮), Liu Fang(刘芳). Determining graphitization and disordered degrees in 2H-graphite by X-Ray diffraction methods [J]. Journal of Test and Measurement Technology(测试技术学报), 2009, 2: 161-167
[18]  Zhang Hua(张华). Modern Organic Wave Spectrum Analysis(现代有机波谱分析) [M]. Beijing: Chemical Industry Press, 2005:250-329
[19]  Han C, Liu Y, Liu C, Ma J, He H. Influence of combustion conditions on hydrophilic properties and microstructure of flame soot [J]. The Journal of Physical Chemistry, 2012, 116: 4129-4136
[20]  Tree D R, Svensson K I. Soot processes in compression ignition engines [J]. Progress in Energy and Combustion Science, 2007, 33:272-309
[21]  Müller J O, Su D S, Wild U, Schlogl R. Bulk and surface structural investigations of diesel engine soot and carbon black [J]. Physical Chemistry Chemical Physics, 2007, 9: 4018-4025
[22]  Park S J, Kim K S. Surface characterization of carbon materials by X-ray photoelectron [J]. Microscopy: Science, Technology, Applications and Education, 2010(1): 1905-1916
[23]  Stanmore B R, Brilhac J F, Gilot P. The oxidation of soot: A review of experiments, mechanisms and models [J]. Carbon, 2001, 39(15): 2247-2268
[24]  Zhang Enhui(张恩惠), Wang Shuyang(汪述洋). The industrialization outlook for bio-oil [J]. Development and Innovation of Machinery and Electrical Products(机电产品开发与创新), 2012,25(1):22-24
[25]  Luo Tingliang(雒廷亮), Xu Qingli(许庆利), Liu Guoji(刘国际), Zhao Jun(赵军),Cao Wenhao(曹文豪). Application prospect of biomass energy [J]. Energy Research and Information(能源研究与信息), 2003, 19(4): 194-197
[26]  Sun Shusheng(孙书生). Research on characteristics of biomass fuel and their using in diesel engine [D]. Hefei: University of Science and Technology of China, 2009
[27]  Wen Dongsheng, Jiang H, Zhang Kai. Supercritical fluids technology for clean biofuel production [J]. Progress in Natural Science, 2009, 19: 273-284

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