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化工学报  2013 

微滴乳液聚合制备PDMS/SiO2纳米复合材料

DOI: 10.3969/j.issn.0438-1157.2013.04.048, PP. 1473-1477

Keywords: 硅溶胶,聚硅氧烷,超声分散,微滴乳液聚合,纳米复合材料

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Abstract:

采用超声分散的方法,以少量八甲基环四硅氧烷(D4)对硅溶胶粒子进行表面接枝改性。然后在改性硅溶胶存在下,以十二烷基苯磺酸(DBSA)为乳化剂兼催化剂进行D4的微滴乳液聚合,得到聚硅氧烷(PDMS)/二氧化硅(SiO2)纳米复合乳液。采用FTIR、TGA、纳米粒度仪、TEM和拉力机分别对样品进行了表征。结果表明:采用超声分散的方法,能够有效地实现硅溶胶粒子的表面改性。通过微滴乳液聚合得到的复合乳胶粒是聚合物包覆二氧化硅粒子的核壳结构形态。SiO2的引入提高了有机硅复合膜力学性能,增强了热稳定性。

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