In an attempt to provide a set of specifications for the use and
trade of the olive pomace in Jordan, several samples of the crude and
laboratory-prepared exhausted (oil-free) olive pomace have been subjected to a
thorough thermochemical characterization.Such
characterization included determination offat content by
using n-hexane and Soxhlet extractor, ultimate and proximate analyses obtained
by using an elemental analyzer and a thermogravimetric procedure, respectively,
gross and net calorific values obtained by using adiabatic oxygen bomb
calorimetry, mineral content (ash), and analysis of the pyrolysis thermograms
in terms of specified temperatures and residual masses associated with such temperatures
as obtained under an inert atmosphere of nitrogen gas at a flow rate of 100 ml
per min and a heating rate of 20°C per minfrom room
temperature up to 600°C.The properties of both the crude and the
exhausted olive pomace were compared. The gross calorific values and
the results of the ultimate analyses for the two pomace types were found to
correlate very well as indicated by the use of a literature correlation formula
usually used for estimating the gross calorific value of a fuel when its
ultimate analysis is known.Other literature correlation formulas used for
estimating thegross calorific value from the proximate analysis data were also
used to check the adequacy of our procedure for getting the proximate analysis
from the thermogravimetric pyrolysis thermograms.
References
[1]
Department of General Statistics, “Agricultural Statistics,” Jordan, 2012.
[2]
S. M. Al-Shdeifat and H. A. Al-Bdour, Annual Report, National Center for Scientific Research and Agricultural Extension, Jordan, 2009.
[3]
K. M. Tawarah, “Thermochemical Characterization of Jordanian Olive Pomace,” Manuscript under Preparation for Publication.
[4]
M. I. Al-Widyan, G. Tashtoush and A. I. Khdair, “Briquettes of Olive Cake as a Potential Source of Thermal Energy,” Journal of Solid Waste Technology and Management, Vol. 28, No. 2, 2002, pp. 51-59.
[5]
M. S. Haddadin, J. Haddadin, O. I. Arabiyat and B. Hattar, “Biological Conversion of Olive Pomace into Compost by Using Trichoderma Harzianum and Phanerochaete Chrysosporium,” Bioresource Technology, Vol. 100, No. 20, 2009, pp. 4773-478. http://dx.doi.org/10.1016/j.biortech.2009.04.047
[6]
M. S. Haddadin and S. M. Abdulrahim, “Solid State Fermentation of Waste Pomace from Olive Processing,” Journal of Chemical Technology and Biotechnology, Vol. 74, No. 7, 1999, pp. 613-618. http://dx.doi.org/10.1002/(SICI)1097-4660(199907)74:7<613::AID-JCTB80>3.0.CO;2-8
[7]
N. Mameri, F. Aioueche, D. Belhocine, H. Grib, H. lounici and D. L. Piron, “Preparation of Activated Carbon from Olive Mill Solid Residue,” Journal of Chemical Technology and Biotechnology, Vol. 75, No. 7, 2000, pp. 625-631. http://dx.doi.org/10.1002/1097-4660(200007)75:7<625::AID-JCTB257>3.0.CO;2-9
[8]
M. L. Cayuela, P. D. Millner, S. L. Meyer and A. Roig, “Potential of Olive Mill Waste and Compost as Bio-Based Pesticides against Weeds, Fungi, and Nematodes,” Science of the Total Environ, Vol. 399, No. 1-3, 2008, pp. 8-11.
[9]
K. R. Cliffe and S. Patumsawad, “Co-Combustion of Waste from Olive Oil Production with Coal in a Fluidized Bed,” Waste Management, Vol. 21, No. 1, 2001, pp. 49- 53. http://dx.doi.org/10.1016/S0956-053X(00)00057-X
[10]
D. Fisher, “Types of Olive Oil for Soap Making Recipes,” 2013. http://candleandsoap.about.com/od/soapmakingoils/a/Types-Of-Olive-Oil-For-Soap-Making-Recipes.htm
[11]
F. Pagnanellia, S. Mainellia, F. Vegli and L. Toroa, “Heavy Metal Removal by Olive Pomace: Biosorbent Characterisation and Equilibrium Modelling,” Chemical Engineering Science, Vol. 58, No. 20, 2003, pp. 4709- 4717. http://dx.doi.org/10.1016/j.ces.2003.08.001
[12]
F. Pagnanelli, L. Toro and F. Veglio, “Olive Mill Solid Residues as Heavy Metal Sorbent Material: A preliminary Study,” Waste Management, Vol. 22, No. 8, 2002, pp. 901-907.
[13]
P. S. Moral and M. V. Méndez, “Production of Pomace Olive Oil,” Grasas y Aceites, Vol. 57, No. 1, 2006, pp. 47-55.
[14]
M. Abu-Qudais, “Fluidized-Bed Combustion for Energy Production from Olive Cake,” Energy, Vol. 21, No. 3, 1996, pp. 173-178. http://dx.doi.org/10.1016/0360-5442(95)00101-8
[15]
M. Abu-Qudais and G. Okasha, “Diesel Fuel and Olive-Cake Slurry: Atomization and Combustion Performance,” Applied Energy, Vol. 54, No. 4, 1996, pp. 315-326. http://dx.doi.org/10.1016/0306-2619(95)00077-1
[16]
T. M. Alkhamis and M. M. Kablan, “Olive Cake as an Energy Source and Catalyst for Oil Shale Production of Energy and Its Impact on the Environment,” Energy Conversion & Management, Vol. 40, No. 17, 1999, pp. 1863- 1870. http://dx.doi.org/10.1016/S0196-8904(99)00023-0
[17]
M. I. Al-Widyan, H. F. Al-Jalil, M. M. Abu-Zreig and N. H. Abu-Hamdeh, “Physical Durability and Stability of Olive Cake Briquettes,” Canadian Biosystems Engineering, Vol. 44, 2002, pp. 341-345.
[18]
Y. H. Khraisha, M. A. Hamdan and H. S. Qalalweh, “Direct Combustion of Oive Cake Using Fluidized Bed Combustor,” Energy Sources, Vol. 21, No. 4, 1999, pp. 319-327. http://dx.doi.org/10.1080/00908319950014803
[19]
S. Meziane, H. Kadi and O. Lamrous, “Kinetic Study of Oil Extraction from Olive Foot Cake, “ Grasas y Aceites, Vol. 57, No. 2, 2006, pp. 175-179.
[20]
S. Kmieciak, S. Meziane, H. Kadi and R. l. Uloussaoui, “Oil Extraction from Olive Foot Cake with Acidic Hexane,” Grasas y Aceites, Vol. 42, No. 1, 1991, pp. 46-50.
ASTM Standard D5865-11A, “Standard Test Method for Gross Calorific Value of Coal and Coke,” Appendix X1, ASTM International, West Conshohocken, 2011.
[23]
K. N. Marsh, “Recommended Reference Materials for the Realization of Physicochemical Properties,” Blackwell, Oxford, 1987.
[24]
S. Gaur and T. B. Reed, “Thermal Data for Natural and Synthetic Fuels,” Marcel Dekker, New York, 1998, p. 259.
[25]
T. Miranda, A. Esteban, S. Rojas, I. Montero and A. Ruiz, “Combustion Analysis of Different Olive Residues,” International Journal of Molecular Science, Vol. 9, No. 4, 2008, pp. 512-525. http://dx.doi.org/10.3390/ijms9040512
L. Meraz, A. Dominguez, I. Kornhauser and F. Roja, “A Thermochemical Concept-Based Equation to Estimate Waste Combustion Enthalpy from Elemental Composition,” Fuel, Vol. 82, No. 12, 2003, pp. 1499-1507. http://dx.doi.org/10.1016/S0016-2361(03)00075-9
[28]
C. Y. Yin, “Prediction of Higher Heating Value of Biomass from Proximate and Ultimate Analyses,” Fuel, Vol. 90, No. 3, 2011, pp. 1128-1132. http://dx.doi.org/10.1016/j.fuel.2010.11.031
[29]
W. Chun-Te and L. Far-Ching, “The Properties of Torrefied Biomass from Six Major Bamboos in Taiwan,” Proceedings of the 55th International Convention of So- ciety of Wood Science and Technology, Beijing, 27-31 August 2012, 8 Pages.
[30]
P. García-Ibanez, M. M. Sánchez and A. A. Cabanillas, “Thermogravimetric Analysis of Olive-Oil Residue in Air Atmosphere,” Fuel Processing Technology, Vol. 87, No. 2, 2006, pp. 103-107. http://dx.doi.org/10.1016/j.fuproc.2005.08.005
[31]
ASTM Standard D3172, “Standard Practice for Proximate Analysis of Coal and Coke,” ASTM International, West Conshohocken, 2007. www.astm.org
[32]
M. C. Mayoral, M. T. Izquierdo, J. M. Andres and B. Rubio, “Different Approaches to Proximate Analysis by Thermogravimetry Analysis,” Thermochimica Acta, Vol. 370, No. 1-2, 2001, pp. 91-97. http://dx.doi.org/10.1016/S0040-6031(00)00789-9
[33]
R. Garcia, C. Pizarro, A. G. Lavin and J. L. Bueno, “Biomass Proximate Analysis Using Thermogravimetry,” Bioresources Technology, Vol. 139, 2013, pp. 1-4. http://dx.doi.org/10.1016/j.biortech.2013.03.197
[34]
M. Varol, “Combustion and Co-Combustion of Olive Cake and Coalina Fluidized Bed,” Thesis, Middle East Technical University, Turkey, 2006.
[35]
J. Parikha, S. A. Channiwalab and G. K. Ghosal, “A Correlation for Calculating HHV from Proximate Analysis of Solid Fuels,” Fuel, Vol. 84, No. 5, 2005, pp. 487-494. http://dx.doi.org/10.1016/j.fuel.2004.10.010