全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...

[5-Hydroxy-3-phenyl-1-(pyridin-2-yl)pyrazol-5-olato]diphenylboron

DOI: 10.1107/s1600536811010634

Full-Text   Cite this paper   Add to My Lib

Abstract:

In the title compound, C26H20BN3O, the B atom has tetrahedral geometry and is linked to two phenyl rings, the O atom of the hydroxypyrazole ring and the N atom of the pyridinyl ring. A six-membered BOCNCN ring forms by coordination of the B atom and the pyridinyl N atom. The BOCNCN ring has an envelope conformation [dihedral angle = 36.7 (1)° between the planar ring atoms and the flap] with the B atom out of the plane. In the 1-(2-pyridinyl)-3-phenyl-5-hydroxypyrazole group, the pyridinyl ring, the phenyl ring and the pyrazole ring are almost coplanar: the pyrazole ring makes a dihedral angle of 9.56 (8)° with the pyridinyl ring and 17.68 (7)° with the phenyl ring. The crystal structure is stabilized by π–π stacking interactions involving the pyridinyl and pyrazole rings of centrosymmetrically related molecules, with ring centroid separations of 3.54 (5) .

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133