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Molecules 2011
Cardanol-Based Materials as Natural Precursors for Olefin MetathesisDOI: 10.3390/molecules16086871 Keywords: Grubbs catalysts, metathesis, pentadecylphenol, cardanol, porphyrins, metallo-porphyrins, fullerenes, fulleropyrrolidines Abstract: Cardanol is a renewable, low cost natural material, widely available as a by-product of the cashew industry. It is a mixture of 3-n-pentadecylphenol, 3-(pentadeca-8-enyl)phenol, 3-(pentadeca-8,11-dienyl)phenol and 3-(pentadeca-8,11,14-trienyl)phenol. Olefin metathesis (OM) reaction on cardanol is an important class of reactions that allows for the synthesis of new olefins that are sometime impossible to prepare via other methods. The application of this natural and renewable material to both academic and industrial research will be discussed.
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