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Molecules  2011 

Cardanol-Based Materials as Natural Precursors for Olefin Metathesis

DOI: 10.3390/molecules16086871

Keywords: Grubbs catalysts, metathesis, pentadecylphenol, cardanol, porphyrins, metallo-porphyrins, fullerenes, fulleropyrrolidines

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Abstract:

Cardanol is a renewable, low cost natural material, widely available as a by-product of the cashew industry. It is a mixture of 3-n-pentadecylphenol, 3-(pentadeca-8-enyl)phenol, 3-(pentadeca-8,11-dienyl)phenol and 3-(pentadeca-8,11,14-trienyl)phenol. Olefin metathesis (OM) reaction on cardanol is an important class of reactions that allows for the synthesis of new olefins that are sometime impossible to prepare via other methods. The application of this natural and renewable material to both academic and industrial research will be discussed.

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