Effects of relative humidity on the characterization of a photochemical smog chamber

Water vapor plays an important role in many atmospheric chemical reactions. A self-made indoor environmental smog chamber was used to investigate the effects of relative humidity (RH) on its characterization, which included the wall effects of reactive species such as O3 and NOx, and the determination of chamber-dependent OH radicals in terms of CO-NOx irradiation experiments. Results showed that the rate constant of O3 wall losses increased with increasing RH, and that their relationship was linearly signi...