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Molecules  1997 

Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes

DOI: 10.3390/jan97p4

Keywords: Photochemistry, pentafluoroiodobenzene, alkene, single electron-transfer, free radical inhibitor

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Abstract:

Irradiation of pentafluoroiodobenzene and alkenes gave the corresponding adducts. The presence of single electron-transfer scavengers, (p-dinitrobenzene and t-Bu2NO) and the free radical inhibitor (hydroquinone) suppressed the reaction. A photoinduced electron-transfer mechanism is proposed.

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