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力学学报  1994 

AN INVESTIGATION OF SURFACE BOUNDARY CONDITIONS FOR CHEMICALLY NON EQUILIBRIUM BOUNDABY LAYERS
化学非平衡边界层壁面边界条件研究

Keywords: boundary layer,chemical reaction,non-equilibrium,surface boundarycondition,ablation
边界层,化学反应,非平衡,壁面边界条件,烧蚀

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Abstract:

The general formulations of the chemically reacting surface boundary condi-tions for non-equilibrium boundary layer chemistry are derived from the theoretical analysisand their specific cases are investigated. When the ablation surface is fully catalystic to allgas phase reactions adjacent to it,the transfer coefficient approach is used to simplify thecalculations by decoupling the ablating surface procedure from a non equilibrium bound-ary layer procedure and a general method for computing the ablation surface parameters isgiven.

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