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物理学报  2012 

Synthesis and growth mechanism of high length-diameter ratio strip-shape diamond by HPHT
高长径比柱状金刚石的高温高压合成与机理研究

Keywords: strip-shape diamond crystal,the length-diameter ratio,segregation
柱状金刚石
,长径比,偏析

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Abstract:

To extend the kind of diamond and solve the low life of diamond tools because of the insufficiency of holding force,the stripshape diamond with more than 2.5 in length-diameter ratio and 0.8—1.0 mm in length is synthesized by optimizing FeNi based catalyst composition and using the technology in the China-type cubic anvil high pressure apparatus.Because of the unique morphology,the threshing phenomenon appearing in the using of diamond tools is controlled effectively.Furthermore,we find that the growth rate of strip-shape diamond is much faster than that of the conventional diamond.Strip-shape diamond morphology and catalyst composition around the growing diamond crystal are characterized by SEM and EDS.The results indicate that the facets of diamond crystal are elongated along {100} and {111} faces and catalyst compositions around the growing diamond crystal become segregated.On this basis,we illustrate the growth mechanism of strip-shape diamond.

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