%0 Journal Article %T Diels-Alder反应研究进展
Research Progress in Diels-Alder Reaction %A 刘飞宇 %A 武雅茹 %A 陈家乐 %A 王崔天 %A 樊晓辉 %J Advances in Material Chemistry %P 326-338 %@ 2331-0146 %D 2025 %I Hans Publishing %R 10.12677/amc.2025.133035 %X Diels-Alder反应作为有机化学中构建六元环骨架的经典反应,因其高效的成环特性与广泛的底物适用性,在医药合成、功能材料开发及生物大分子修饰等领域具有不可替代的重要地位。近年来,随着催化技术的持续革新,该反应在催化体系设计、立体选择性调控及绿色合成路径开发等方向取得了突破性进展。本文以催化体系为核心脉络,系统综述近年来金属催化、有机催化及手性催化Diels-Alder反应的研究成果,为拓展其在复杂分子合成、新型材料制备等前沿领域的应用提供参考。
The Diels-Alder reaction, as a classic method for constructing six-membered ring frameworks in organic chemistry, holds an irreplaceable and important position in fields such as pharmaceutical synthesis, functional materials development, and biomolecule modification due to its efficient ring-forming characteristics and broad substrate applicability. In recent years, with the continuous innovation of catalytic technologies, this reaction has made groundbreaking progress in areas such as catalytic system design, stereoselectivity regulation, and the development of green synthesis pathways. This article focuses on catalytic systems and systematically reviews the latest research achievements in metal-catalyzed, organic-catalyzed, and chiral-catalyzed Diels-Alder reactions in recent years, aiming to provide strategic references for expanding its applications in cutting-edge fields such as complex molecule synthesis and novel material preparation. %K Diels-Alder反应, %K 金属催化, %K 有机催化, %K 手性催化
Diels-Alder Reaction %K Metal Catalysis %K Organic Catalysis %K Chiral Catalysis %U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=119763