%0 Journal Article
%T 冠醚在多孔材料的研究进展<br>Research Progress of Crown Ethers in Porous Materials
%A 孙朴
%A 韩宇霞
%A 吕洁
%J Advances in Analytical Chemistry
%P 123-133
%@ 2163-1565
%D 2025
%I Hans Publishing
%R 10.12677/aac.2025.152013
%X 冠醚(Crown Ethers)是一类具有特定环状空腔结构的化合物&#65292;从较小的环到较大的多环结构都有(如14-冠-4醚、15-冠-5醚、18-冠-6醚等等)&#65292;这种特殊的环状结构和尺寸大小赋予了冠醚独特的物理和化学性质&#65292;其独特的离子识别能力为高效离子分离提供了新的解决方案。本文综述了冠醚功能化多孔材料(包括金属有机框架MOFs、共价有机框架COFs、介孔二氧化硅MS)的设计原理、实验结果分析及其在相关领域的应用进展和未来发展方向。<br>Crown ethers are a class of compounds with specific cyclic cavity structures, ranging from smaller rings to larger polycyclic structures (such as 14-crown-4 ether, 15-crown-5 ether, 18-crown-6 ether, etc.). This special cyclic structure and size give crown ether unique physical and chemical properties, and its unique ion recognition ability provides a new solution for efficient ion separation. In this paper, the design principles, experimental results and application progress and future development direction of crown ether functionalized porous materials (including metal-organic framework MOFs, covalent organic framework COFs, and mesoporous silica MS) are reviewed.
%K 冠醚&#65292
%K 多孔材料&#65292
%K MOFs&#65292
%K COFs&#65292
%K MS&#65292
%K 离子分离<br>Crown Ether
%K Porous Materials
%K MOFs
%K COFs
%K MS
%K Ion Separation
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=112291