%0 Journal Article
%T CuInS<sub>2</sub>/ZnS核/壳量子点与碳点复合结构荧光粉制备与光电性质研究<br>Preparation and Photoelectric Properties of CuInS<sub>2</sub>/ZnS Core/Shell Quantum Dots and Carbon Dots Composite Phosphors
%A 王静
%A 孙明烨
%A 张蕾
%A 张冰
%J Material Sciences
%P 308-316
%@ 2160-7621
%D 2025
%I Hans Publishing
%R 10.12677/ms.2025.152036
%X 本文利用胶体化学法合成红光发射的油相CuInS<sub>2</sub>/ZnS核/壳量子点。利用3-巯基丙酸对油相CuInS<sub>2</sub>/ZnS核/壳量子点进行配体交换&#65292;实现从油相量子点到水相量子点的转换。将其与绿光发射的亲水性碳点复合&#65292;抑制碳点的固态聚集荧光猝灭&#65292;并通过引入碳点绿光发射&#65292;制备得到近白光发射的CuInS<sub>2</sub>/ZnS核/壳量子点与碳点的复合结构荧光粉&#65292;后利用傅里叶变换红外光谱和X射线光电子谱对其结构与组成进行了表征。并将近白光发射的复合结构荧光粉应用于制备LED照明器件&#65292;得到色坐标为(0.4146, 0.4101)的暖白光发射照明器件。<br>Red-emitting oil-phase CuInS<sub>2</sub>/ZnS core/shell quantum dots are synthesized by colloidal chemistry. The oil-phase CuInS<sub>2</sub>/ZnS core/shell quantum dots are converted to water-phase quantum dots through ligand exchange with 3-mercaptopropionic acid. They are then combined with hydrophilic green-emitting carbon dots to suppress the solid-state aggregation quenching of carbon dots. By introducing the green emission of carbon dots, a near-white-emitting composite phosphor of CuInS<sub>2</sub>/ZnS core/shell quantum dots and carbon dots is prepared. The structure and composition of the phosphor are characterized by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The near-white-emitting composite phosphor is then applied to the fabrication of LED lighting devices, resulting in a warm white light-emitting device with a color coordinate of (0.4146, 0.4101).
%K CuInS<sub>2</sub>量子点&#65292
%K 碳点&#65292
%K 荧光粉<br>CuInS<sub>2</sub> Quantum Dots
%K Carbon Dots
%K Phosphors
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=108105