%0 Journal Article
%T 烯基高价碘的合成研究进展<br>Research Progress in the Synthesis of Alkenyl Hypervalent Iodine
%A 刘冰杰
%J Journal of Organic Chemistry Research
%P 549-559
%@ 2330-524X
%D 2024
%I Hans Publishing
%R 10.12677/jocr.2024.124053
%X 近年来&#65292;有机高价碘试剂的反应性研究获得了迅猛的发展。有机高价碘试剂作为高效、多功能化的氧化剂&#65292;通常容易制备且操作简单。与传统的合成方法相比&#65292;该类试剂参与的反应表现出了许多独特的优点&#65292;并且具有与汞、铬、铅、铊等重金属试剂类似的反应性&#65292;但却没有这些试剂所带来的毒性和环境污染问题。基于此&#65292;有机高价碘试剂引起了化学合成工作者们越来越多的关注。但是笔者发现目前有机高价碘的反应报道绝大部分都是芳基高价碘&#65292;有关烯基高价碘的报道却寥寥无几。本文介绍有关芳基高价碘不同的反应性能和探索烯基高价碘的合成。<br>In recent years, the reactivity studies of organic hypervalent iodine reagents have gained rapid development. Organic hypervalent iodine reagents, as highly efficient and versatile oxidizing agents, are usually easy to prepare and simple to operate. Compared with conventional synthesis methods, the reactions involving these reagents exhibit many unique advantages and have similar reactivity to heavy metal reagents such as mercury, chromium, lead, thallium, etc., but without the toxicity and environmental pollution problems associated with these reagents. In this way, organic hypervalent iodine reagents have attracted more and more attention from the chemical synthesizers. However, the author found that most of the reports on the reactions of organic hypervalent iodine are aryl hypervalent iodine, and only a few reports on alkenyl hypervalent iodine. In this paper, we introduce the different reaction properties of aryl iodides and explore the synthesis of alkenyl iodides.
%K 有机高价碘&#65292
%K 烯基高价碘<br>Organic Hypervalent Iodine
%K Alkenyl Hypervalent Iodine
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=104197