%0 Journal Article
%T 锌–稀土单分子磁体的研究进展
Research Progress in Zn-Ln Single Molecule Magnets
%A 胡翔宇
%A 梁皓然
%A 徐嘉琦
%A 解梦婷
%A 王窦尊
%A 郑祺
%A 崔会会
%J Journal of Advances in Physical Chemistry
%P 795-809
%@ 2168-6130
%D 2024
%I Hans Publishing
%R 10.12677/japc.2024.134079
%X 锌(II) d轨道的电子是全充满的，它通过与配体形成配位键。在结构中提供金属骨架，并通过桥联配体与稀土元素连接，间接影响稀土离子的磁性行为。近年来，锌–稀土金属配合物在分子磁性材料领域受到广泛关注，因此，本文通过对近年来典型的锌–稀土单分子磁体进行综述，以期为3d-4f单分子磁体的发展奠定一定的基础。
The electrons of the zinc(II) d orbital are fully filled, which can form coordination bonds with ligands. It provides a metal skeleton in the structure and is connected to lanthanide elements by bridging ligands, indirectly affecting the magnetic behavior of lanthanide ions. In recent years, zinc-lanthanide metal complexes have received extensive attention in the field of molecular magnetic materials. Therefore, this paper reviews the typical zinc-lanthanide single molecule magnets (SMMs) in recent years, hoping to lay a certain foundation for the development of 3d-4f SMMs.
%K 锌–
%K 稀土单分子磁体，
%K 结构，
%K 磁性
Zn-Ln Single Molecule Magnets
%K Structure
%K Magnetism
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=101651