%0 Journal Article
%T 无金属介入的去芳香化反应研究进展<br>Research Progress of Dearomatization Reactions without Metal Intervention
%A 李瑞琦
%J Journal of Organic Chemistry Research
%P 119-126
%@ 2330-524X
%D 2022
%I Hans Publishing
%R 10.12677/JOCR.2022.104012
%X 一些易得的芳香族原料和复杂大分子的中间体可以通过去芳香化反应合成，因此在过去十年中，去芳香化反应的迅速发展为天然产物提供了新的合成方法。本综述将重点介绍非金属催化条件下去芳香化反应的研究进展以及各类策略在合成应用方面的进展，并将去芳香化反应分为以下几类，包括氧化还原型去芳香化反应、亲核亲电型去芳香化反应和环加成型去芳香化反应。<br />
Some readily available aromatic feedstocks and intermediates of complex macromolecules can be synthesized by dearomatization reactions, so the rapid development of dearomatization reactions in the last decade has provided new synthesis methods for natural products. This review will focus on the research progress of dearomatization reactions under non-metallic catalytic conditions and the progress of various strategies in synthetic applications and will classify dearomatization reactions into the following categories, including REDOX dearomatization reactions, nucleophilic and electrophilic dearomatization reactions and cycloadditive dearomatization reactions.
%K 芳烃，去芳香化，无金属介入<br>Arene
%K Dearomatization Reactions
%K Metal Free Reaction
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=58438