%0 Journal Article
%T 光稳定剂中间体2-氯-4,6-二(N-丁基-2,2,6,6-四甲基-4-哌啶胺基)-1,3,5-三嗪的合成研究<br>Synthetic Research of Light Stabilizer Intermediate 2-Chloro-4,6-Bis(N-Butyl- 2,2,6,6-Tetramethyl-4-Piperidinyl)-1,3,5-Triazine
%A 李建华
%A 喻红梅
%A 华平
%A 朱国华
%J Journal of Advances in Physical Chemistry
%P 91-96
%@ 2168-6130
%D 2021
%I Hans Publishing
%R 10.12677/JAPC.2021.103009
%X 采用单因素法，以三聚氯氰、N-丁基-2,2,6,6-四甲基-4-哌啶胺和氢氧化钠为原料，二甲苯为溶剂，四丁基溴化铵为催化剂合成光稳定剂中间体2-氯-4,6-二(N-丁基-2,2,6,6-四甲基-4-哌啶胺基)-1,3,5-三嗪。结果表明该反应的最优工艺条件为第一阶段反应温度为5℃~8℃，反应时间2 h，第二阶段升温至60℃，反应时间5 h，原料物质的量之比n(三聚氯氰):n(N-丁基-2,2,6,6-四甲基-4-哌啶胺):n(氢氧化钠) = 1:2.15:2.15，催化剂四丁基溴化铵的用量0.20 g (相对0.05 mol三聚氯氰)，产品产率为95.61%。<br />
The light stabilizer intermediate 2-chloro-4,6-bis(n-butyl-2,2,6,6-tetramethyl-4-piperidinyl)-1,3,5- triazine was synthesized by single factor method with cyanuric chloride, n-butyl-2,2,6,6-tetra- me-thyl-4-piperidinyl and sodium hydroxide as raw materials, xylene as solvent and tetrabutyl ammo-nium bromide as catalyst. The results showed that the optimum reaction conditions were as follows: the reaction temperature in the first stage was 5？C~8？C, the reaction time was 2 h, the temperature in the second stage was raised to 60？C, the reaction time was 5 h, the ratio of raw material n(cyanuric chloride):n(n-butyl-2,2,6,6-tetramethyl-4-piperidine):n(sodium hydroxide) = 1:2.15:2.15, the amount of catalyst tetrabutyl ammonium bromide was 0.20 g (relative to 0.05 mol cyanuric chloride), the yield of the product was 95.61%.
%K 光稳定剂，三聚氯氰，N-丁基-2
%K 2
%K 6
%K 6-四甲基-4-哌啶胺，2-氯-4
%K 6-二(N-丁基-2
%K 2
%K 6
%K 6-四甲基-4-哌啶胺基)-1
%K 3
%K 5-三嗪<br>Light Stabilizer
%K Cyanuric Chloride
%K N-Butyl-2
%K 2
%K 6
%K 6-Tetramethyl-4-Piperidine Amine
%K 2-Chloro-4
%K 6-Bis(N-Butyl-2
%K 2
%K 6
%K 6-Tetramethyl-4-Piperidine Amine)-1
%K 3
%K 5-Triazine
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=44699