%0 Journal Article
%T Radical-Organometallic Hybrid Reaction System Enabling Couplings between Tertiary-Alkyl Groups and 1-Alkenyl Groups
%J -
%D 2018
%R https://doi.org/10.1021/acscatal.8b01572
%X Suzuki¨CMiyaura couplings of tertiary-alkyl moieties are accomplished in the presence of a copper catalyst, in which quaternary carbons possessing various functional groups can be synthesized via a radical reaction. Mechanistic studies revealed that 1-alkenylcopperI plays an important role in this coupling reaction. We expect that the radical-organometallic combined process will become one of the best options for the synthesis of quaternary carbons
%U https://pubs.acs.org/doi/10.1021/acscatal.8b01572