%0 Journal Article
%T Encapsulation of LiFePO4 Nanoparticles into 3D Interpenetrating Ordered Mesoporous Carbon as a High-Performance Cathode for Lithium-Ion Batteries Exceeding Theoretical Capacity
%J -
%D 2019
%R https://doi.org/10.1021/acsaem.8b01682
%X A nanocomposite cathode based on LiFePO4 (LF) nanoparticles embedded 3D cubic ordered mesoporous carbon CMK-8 for lithium-ion batteries is synthesized by a facile impregnation method followed by further modification with carbon coating. The effects of variation of carbon contents on electrochemical performances of cathodes are investigated. The highly crystalline nanophase of LiFePO4 particles is confirmed by X-ray diffraction and TEM analysis. Nitrogen adsorption每desorption isotherms reveal persistence mesoporosity after encapsulation of LiFePO4 nanoparticles. The graphitic phase in LF/[email protected]X (X = amount of CMK-8) nanocomposites is detected by analyzing the Raman spectra of the matrix carbon due to CMK-8 and the coated carbon (C). The electrochemical properties of the LF/[email protected]X nanocomposites are evaluated with cyclic voltammetry, impedance spectroscopy, and charge每discharge cycling. The excellent rate capability with a discharge capacity value of 184.8 mA h g每1 is obtained for LF/[email protected] nanocomposite electrode at a current rate of 0.05C, which is higher than the theoretical capacity of LiFePO4 (170 mA h g每1). The discharge capacity (178.3 mA h g每1) is higher than the theoretical capacity up to the current rate of 0.2C. The long cycle stability test at a higher current rate of 10C exhibits remarkable discharge capacity of 120 mA h g每1 with 96.7% capacity retention after 1000 cycles and demonstrates the great potential of LF/[email protected] nanocomposite cathode for use in lithium-ion batteries
%U https://pubs.acs.org/doi/10.1021/acsaem.8b01682