%0 Journal Article
%T Boosting the Deep Discharging/Charging Lithium Storage Performances of Li3VO4 through Double-Carbon Decoration
%J -
%D 2018
%R https://doi.org/10.1021/acsami.8b08483
%X With high theoretical capacity, good ionic conductivity, and suitable working plateaus, Li3VO4 has emerged as an eye-catching intercalation anode material for lithium storage. However, Li3VO4 suffers from poor electrical conductivity and 20% volume variation under deep discharging/charging conditions. Herein, we present a ˇ°double-carbon decorationˇ± strategy to tackle both issues. Deflated balloon-like Li3VO4/C/reduced graphene oxide (LVO/C/rGO) microspheres with continuous electron transport pathways and sufficient free space for volume change accommodation are fabricated through a facile spray-drying method. Under deep discharging/charging conditions (0.02¨C3.0 V), LVO/C/rGO achieves a high intercalation capacity of 591 mA h g¨C1. With high capacity and outstanding stability, LVO/C/rGO outperforms other intercalation anode materials (such as graphite, Li4Ti5O12, and TiO2). In situ X-ray diffraction measurement reveals that the lithium storage is realized through both solid-solution reaction and two-phase reaction mechanisms. A LVO/C/rGO//LiNi0.8Co0.15Al0.05O2 lithium-ion full cell is also assembled. In such full cell, LVO/C/rGO also demonstrates high specific capacity and excellent cycling stability. The above results manifest that the LVO/C/rGO anode has the potential to be applied in the next-generation high-performance lithium-ion batteries
%U https://pubs.acs.org/doi/10.1021/acsami.8b08483