%0 Journal Article
%T Hydrogen-Bonding-Assisted Br£¿nsted Acid and Gold Catalysis: Access to Both (E)- and (Z)-1,2-Haloalkenes via Hydrochlorination of Haloalkynes
%J -
%D 2018
%R https://doi.org/10.1021/acscatal.7b03563
%X We have developed an efficient synthesis of both (Z)- and (E)-chlorohaloalkenes via hydrochlorination of haloalkynes, based on two distinct hydrogen-bond-network-assisted catalytic systems: Br£¿nsted acid catalysis and gold catalysis. Both systems offer high stereoselectivity, good chemical yields, and diverse functional group tolerance
%U https://pubs.acs.org/doi/10.1021/acscatal.7b03563