%0 Journal Article %T Fabrication of MOF Thin Films at Miscible Liquid¨CLiquid Interface by Spray Method %J - %D 2018 %R https://doi.org/10.1021/acsami.8b09812 %X Metal¨Corganic frameworks (MOFs) are an intriguing class of porous crystalline inorganic¨Corganic hybrid materials. The fabrication of oriented, crystalline thin film of MOFs is expected to open novel avenues to traditional applications and to serve myriad advanced technologies. Here, a facile spray-assisted miscible liquid¨Cliquid interface (MLLI) synthetic strategy is carried out and reported under mild condition that utilizes miscible interface for the rapid and controllable fabrication of large-area free-standing MOF thin films. The methodology can employ various metal nodes and organic ligands to yield various high quality lamellar/granulous MOF thin films at MLLI, which indicates the universality of the MLLI strategy %U https://pubs.acs.org/doi/10.1021/acsami.8b09812