%0 Journal Article
%T Multidirection Piezoelectricity in Mono- and Multilayered Hexagonal ¦Á-In2Se3
%J -
%D 2018
%R https://doi.org/10.1021/acsnano.8b02152
%X Piezoelectric materials have been widely used for sensors, actuators, electronics, and energy conversion. Two-dimensional (2D) ultrathin semiconductors, such as monolayer h-BN and MoS2 with their atom-level geometry, are currently emerging as new and attractive members of the piezoelectric family. However, their piezoelectric polarization is commonly limited to the in-plane direction of odd-number ultrathin layers, largely restricting their application in integrated nanoelectromechanical systems. Recently, theoretical calculations have predicted the existence of out-of-plane and in-plane piezoelectricity in monolayer ¦Á-In2Se3. Here, we experimentally report the coexistence of out-of-plane and in-plane piezoelectricity in monolayer to bulk ¦Á-In2Se3, attributed to their noncentrosymmetry originating from the hexagonal stacking. Specifically, the corresponding d33 piezoelectric coefficient of ¦Á-In2Se3 increases from 0.34 pm/V (monolayer) to 5.6 pm/V (bulk) without any odd¨Ceven effect. In addition, we also demonstrate a type of ¦Á-In2Se3-based flexible piezoelectric nanogenerator as an energy-harvesting cell and electronic skin. The out-of-plane and in-plane piezoelectricity in ¦Á-In2Se3 flakes offers an opportunity to enable both directional and nondirectional piezoelectric devices to be applicable for self-powered systems and adaptive and strain-tunable electronics/optoelectronics
%U https://pubs.acs.org/doi/10.1021/acsnano.8b02152