%0 Journal Article
%T Surface Modification of Silicon Nanoparticles by an “Ink” Layer for Advanced Lithium Ion Batteries
%J -
%D 2018
%R https://doi.org/10.1021/acsami.8b03000
%X Owing to its high specific capacity, silicon is considered as a promising anode material for lithium ion batteries (LIBs). However, the synthesis strategies for previous silicon-based anode materials with a delicate hierarchical structure are complicated or hazardous. Here, Prussian blue analogues (PBAs), widely used in ink, are deposited on the silicon nanoparticle surface ([email protected]) to modify silicon nanoparticles with transition metal atoms and a N-doped carbon layer. A facile and green synthesis procedure of [email protected] nanocomposites was carried out in a coprecipitation process, combined with a thermal treatment process at 450 °C. As-prepared [email protected] delivers a reversible charge capacity of 725.02 mAh g–1 at 0.42 A g–1 after 200 cycles. Moreover, this [email protected] composite exhibits an exceptional rate performance of ～1203 and 263 mAh g–1 at current densities of 0.42 and 14 A g–1, respectively, and fully recovered to 1136 mAh g–1 with the current density returning to 0.42 A g–1. Such a novel architecture of [email protected] via a facile fabrication process represents a promising candidate with a high-performance silicon-based anode for LIBs
%U https://pubs.acs.org/doi/10.1021/acsami.8b03000