%0 Journal Article
%T 3,3¡ä-(Diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide]
%A Alexander Larin
%A Igor Ovchinnikov
%A Leonid Fershtat
%A Nina Makhova
%J -
%D 2018
%R https://doi.org/10.3390/M1003
%X Abstract The nitramino derivatives of furoxans are of specific interest as precursors for the preparation of high energy salts with nitrogen-rich cations. In this communication, the 3,3¡ä-(diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide] was prepared via nitration of available 4,4¡ä-diamino-3,3¡ä-diazenofuroxan; the best yield of the target compound was achieved under the action of nitrating system HNO 3/(CF 3CO) 2O in molar ratio 15:3 in CCl 4 at £¿5 ¡ãC. The structure of 3,3¡ä-(diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide] was confirmed by means of 1H, 13C, 14N-NMR, IR spectroscopy and high resolution mass spectra (HRMS). View Full-Tex
%K 3
%K 3¡ä-(diazene-1
%K 2-diyl)bis[4-(nitroamino)-1
%K 2
%K 5-oxadiazole 2-oxide]
%K 4
%K 4¡ä-diamino-3
%K 3¡ä-diazenofuroxan
%K nitration
%U https://www.mdpi.com/1422-8599/2018/3/M1003