%0 Journal Article
%T Synthesis of the ABCDG ring skeleton of communesin F based on carboborylation of 1,3-diene and Bi(OTf)3-catalyzed cyclizations
%J -
%D 2019
%R https://doi.org/10.1038/s41429-019-0142-7
%X Communesins, isolated from the mycelium of a strain of Penicillium sp., are cytotoxic heptacyclic indole alkaloids bearing a bis-aminal structure and two contiguous quaternary carbon centers. Toward a total synthesis of communesin F, we synthesized a pentacyclic ABCDG ring skeleton via carboborylation of 1,3-diene and a Friedel¨CCrafts-type cyclization, resulting in the formation of an azepine ring through a Bi(OTf)3-catalyzed SN2¡¯ reaction
%U https://www.nature.com/articles/s41429-019-0142-7