%0 Journal Article
%T Bimetallic Pd-Cu-composites of polyaniline in electrocatalytic hydrogenation of phenylacetylene
%A Elena Anatolievna Soboleva
%A Nina Mikhailovna Ivanova
%A Yakha Akhmadovna Visurkhanova
%J -
%D 2017
%R https://doi.org/10.15328/cb773
%X Bimetallic Pd-Cu-composites of polyaniline prepared by introducing metals (II) chlorides in the process of oxida-tive polymerization of aniline with and without chemical reduction by sodium borohydride are applied to copper cath-ode activation in electrohydrogenation of phenylacetylene in basic aqueous ethanolic solutions of catholyte. Electro-catalytic activity of composites that they exhibited in the process is due to formation of metal particles (and their al-loys) by electrochemical reduction of metal cations in the polymer matrix. The main hydrogenation products are ethyl benzene and 1,4-diphenylbutane, the yields of which influence metal content in the studied composites.
%U https://bulletin.chemistry.kz/index.php/kaznu/article/view/773