%0 Journal Article
%T ¦Â-Hydrosilylation of Allylic Derivatives with Cyclic and Linear Siloxanes in the Presence of Platinum Catalysts
%A Zainab Rbihi
%A Salah Eddine Lanaya
%A Mohamed Yassine Guida
%A El Mostapha Rakib
%A Abdelatif Barakat
%A Abdelghani El Malki
%A Abdellah Hannioui
%J Open Access Library Journal
%V 8
%N 4
%P 1-17
%@ 2333-9721
%D 2021
%I Open Access Library
%R 10.4236/oalib.1107364
%X The aim of this work is to study the influence of the nature and position of substitution at allyl benzene on the regioselectivity of the hydrosilylation reaction. We studied hydrosilylation of the various allyl derivatives with cyclic siloxane, D<sub>4</sub><sup style="margin-left:-7px;">H</sup>, and linears hydrosilylating agents, 1,1,3,3-tetramethyldisiloxane and MD<sup>H</sup>M, in the presence of platinum-based catalysts (Karstedt catalyst, platinum black). We also show the effects of the amount of catalyst on the conversion. Moreover, the influence on the temperature on catalytic activity and selectivity of the hydrosilylation reaction was explained. All new compounds were characterized by <sup>1</sup>H, <sup>13</sup>C, <sup>29</sup>Si NMR and HRMS as well.
%K Allylbenzene Derivatives
%K Karstedt¡¯s-Catalyst
%K Hydrosilylation
%K Siloxane
%K Platinum Black
%U http://www.oalib.com/paper/6528096