%0 Journal Article %T SIS-g-AN热降解性能的研究 %A 杨性坤 %A 胡付欣 %J - %D 2005 %X 采用热重分析法和差示热重分析法研究丙烯腈(AN)接枝热塑性弹性体SIS(SIS-g-AN)的热降解性能。结果得出,SIS-g-AN的平衡起始降解温度、平衡最大降解速率温度和平衡终止降解温度分别为659.17,713.94和740.05 K;热降解反应活化能为195.2 kJ·mol-1;热降解机理是Deceleration中的D3降解机理;不同质量损失率下的热寿命与温度呈线性关系。;The thermal degradation of SIS-g-AN was investigated by thermogravimetry and differential thermogravimetry.The results showed that the equilibrium temperatures of SIS-g-AN at degradation starting,maximum degradation rate and degradation end were 659.17,713.94 and 740.05 K respectively;the activation energy in thermal degradation process was 195.5 kJ·mol-1;the thermal degradation mechanism obeyed D3 in Deceleration;and the thermal lifetimes at various weight loss rates were linear with temperatures %K [热塑性弹性体SIS %K 丙烯腈 %K 接枝共聚物 %K 热降解性能 %K 热重分析 %K 差示热重分析 %K 热塑性弹性体SIS %K 丙烯腈 %K 接枝共聚物 %K 热降解性能 %K 热重分析 %K 差示热重分析 %K SIS %K acrylnitrile %K graft copolymer %K thermal degradation %K thermalgravimetry %K differential thermogravimetry] %U http://www.rubbertire.cn/gy/xjgy/ch/reader/view_abstract.aspx?file_no=xj20050503&flag=1