%0 Journal Article
%T 可见光深度催化氧化脱硫研究
Deep Photocatalytic Desulfurization of Fuel under Visible Light
%A 张宗伟
%A 李酽
%A 初飞雪
%A 林霞
%J -
%D 2014
%X 以溶胶-凝胶法制备了纳米TiO2和稀土离子Eu3+、Nd3+掺杂的TiO2,并以TiO2和核黄素溶液为催化剂氙灯照射光催化深度去除油品中苯并噻吩,考察了氧化剂、双氧水浓度、核黄素浓度等工艺条件的影响。结果表明:体积浓度为25;的双氧水脱硫效果较好,当核黄素浓度达到25μg ? mL-1时,脱硫率达到最高,稀土掺杂TiO2后可提高油品硫的脱除率,TiO2光响应范围向可见光拓展。
Nano-TiO2 were prepared by sol-gel progress. Eu3+,Nd3+ were adoped to enhance the photocatalytic ac-tivity under visible light. The degradation of benzobthiophene in jet fuel was investigated by TiO2 catalyst and ribo-flavin solution under xenon lamp. The results indicate that Lanthanon into titania could efficiently extend photoactiv-ity and expand the visible light response range. The desulfurization rate was high under 25; H2 O2 volume fraction. The desulfurization rate reaches to 78. 85; using Eu-TiO2
%K TiO2
%K 稀土掺杂
%K 苯并噻吩
TiO2 稀土掺杂 苯并噻吩
%K TiO2 稀土掺杂 苯并噻吩
%K TiO2 稀土掺杂 苯并噻吩
%U http://lkxb.jxnu.edu.cn//oa/darticle.aspx?type=view&id=20140322