%0 Journal Article
%T 四甲基二甲酰型芳环化合物的合成<br>The Synthesis of Di-Methylbenzoyl Phenyl Compounds
%A 洪慧铭
%A 王利云
%A 宋 ?b
%A 唐传超
%A 姚大林
%A 喻国生
%A 陈 海
%A 宋才生
%J -
%D 2018
%R 10.16357/j.cnki.issn1000-5862.2018.01.15
%X 双酮酐型聚酰亚胺(PI)具有优异的耐热性能及力学性能,制备此类型聚酰亚胺的重要单体之一是多烷基化合物.通过低温Friedel-Crafts酰基化反应制备1,4-二(3',4'-二甲基苯甲酰基)苯、1,3-二(3',4'-二甲基苯甲酰基)苯、4,4'-二(3',4'-二甲基苯甲酰基)二苯醚、4,4'-二(3',4'-二甲基苯甲酰基)联苯4种四甲基二甲酰型芳环化合物,并且分别对4种化合物的结构进行了红外和核磁分析.结果表明:所得4种化合物与目标产物一致,有望拓展双酮型二酐的种类,进而合成性能更佳的新型双酮酐型聚酰亚胺.<br>Di-ketone dianhydride polyimides have excellent thermal stability and good mechanical properties in high temperature.Design and synthesis the novel alkyl anhydride is important to the industry of polyimides.1,4-di(3',4'-dimethybenzoyl)benzene,1,3-di(3',4'-dimethybenzoyl)benzene,4,4-di(3',4'-dimethybenzoyl)diphenyl ether and 4,4-di(3',4'-dimethybenzoyl)biphenyl are prepared by Friedel-Crafts acylation in this work and are characterized by FT-IR and 1H NMR.The results show that the structures of four compounds are target compounds.Novel high performance polyimide with di-ketone anhydride groups can be synthesized by these alkyl dianhydrides
%K 四甲基二甲酰
%K 双酮二酐
%K 双酮酐型聚酰亚胺<br>四甲基二甲酰 双酮二酐 双酮酐型聚酰亚胺
%K 四甲基二甲酰 双酮二酐 双酮酐型聚酰亚胺
%K 四甲基二甲酰 双酮二酐 双酮酐型聚酰亚胺
%U http://lkxb.jxnu.edu.cn//oa/darticle.aspx?type=view&id=201801015