%0 Journal Article %T 多壁碳纳米管/聚(丙三醇-癸二酸-柠檬酸)酯弹性体复合材料的制备与性能研究 %A 刘全勇 %A 吴珺玥 %A 张立群 %A 石锐 %A 雷丽娟 %J - %D 2009 %X 采用熔融共缩聚反应法合成聚(丙三醇-癸二酸-柠檬酸)酯(PGSC)弹性体,再采用半原位聚合和研磨分散的方法制备多壁碳纳米管(MWCNT)/PGSC复合材料,并对复合材料的性能进行研究。结果表明,MWCNT对PGSC的玻璃化温度影响不大;随着MWCNT用量的增大,MWCNT/PGSC复合材料的弹性模量和拉伸强度总体增大,溶胀度和吸水率逐渐减小;当MWCNT用量达到或超过1份时,与PGSC相比,MWCNT/PGSC复合材料的弹性模量和拉伸强度较大,降解速率较小。;A poly(glycerol-sebacate-citrate)(PGSC) elastomer was synthesized by melting copolycondensation,then a MWCNT/PGSC composite was prepared by semi-in-situ polymerization and grinding dispersion method,and the properties of composite were investigated.The results showed that the MWCNT had little effect on the glass transition temperature of PGSC;as the addition level of MWCNT increased,the elastic modulus and tensile strength of MWCNT/PGSC composite increased,the swelling degree and water absorption decreased;when the addition level of MWCNT reached or exceeded 1 phr,the elastic modulus and tensile strength of MWCNT/PGSC composite were higher than those of PGSC,and the degradation rate was lower %K [聚(丙三醇-癸二酸-柠檬酸)酯弹性体 %K 多壁碳纳米管 %K 复合材料 %K 生物降解 %K 聚(丙三醇-癸二酸-柠檬酸)酯弹性体 %K 多壁碳纳米管 %K 复合材料 %K 生物降解 %K poly(glycerol-sebacate-citrate) elastomer %K MWCNT %K composite %K biodegradation] %U http://www.rubbertire.cn/gy/xjgy/ch/reader/view_abstract.aspx?file_no=XJ20091106&flag=1