%0 Journal Article %T 杜仲橡胶硫化胶交联密度与结晶性能关系研究 %A 刘天琦 %A 方庆红 %A 胡之朗 %J - %D 2013 %X 采用差示扫描量热(DSC)法分析杜仲橡胶硫化胶交联密度对其物理性能和结晶性能的影响。结果表明:随着硫黄用量的增大,杜仲橡胶硫化胶的交联密度增大,邵尔A型硬度减小,100%定伸应力、拉伸强度和拉断伸长率先增大后减小;消除热历史后杜仲橡胶生胶的结晶特征减弱;随着交联密度的增大,硫化胶的DSC特征熔融峰减弱直至消失,结晶峰钝化,峰面积减小。;The effect of cross-linking density of gutta-percha rubber vulcanizate on its physical properties and crystallization characteristics was investigated by differential scanning calorimetry(DSC) method.The results showed that,as the addition level of sulfur increased,the cross-linking density of gutta-percha rubber vulcanizate increased,the Shore A hardness decreased,and the modulus at 100% elongation,tensile strength and elongation at break were increased at first and then decreased.After eliminating thermal history,the crystallization characteristic of gum rubber was weakened.When the cross-linking density increased,the melting peaks were weakened until they disappeared,the crystallization peaks became small and broad,and the area of crystallization peak decreased %K [杜仲橡胶 %K 交联密度 %K 结晶性能 %K 杜仲橡胶 %K 交联密度 %K 结晶性能 %K gutta-percha rubber %K cross-linking density %K crystallization characteristic] %U http://www.rubbertire.cn/gy/xjgy/ch/reader/view_abstract.aspx?file_no=XJ20131003&flag=1