%0 Journal Article %T 环氧化天然橡胶/PVC共混物的热氧降解 %A 刘惠伦 %A 张北龙 %J - %D 2001 %X 采用热重-差示热重分析和差热分析研究了环氧化天然橡胶(ENR)/PVC共混物的热氧降解过程。结果表明,炭黑补强的ENR/PVC共混物的热氧降解过程分为3个阶段,第1阶段主要是PVC脱氯化氢,而氯化氢引起ENR发生催化氧化反应而放热,且该阶段明显受到ENR/PVC共混比的影响,随着PVC用量的增大,共混物的热氧稳定性下降。;The thermo-oxidative degradation of ENR/PVC blend was investigated by TG-DTG and DTA.The results showed that the degradation process of ENR/PVC blend filled with carbon black consisted of three steps;the exothermic HCl-catalysed oxidative reaction of ENRwas resulted from giving-off of HCl during the first step;and the first step of degradation process was affected by the blending ratio of ENR/PVC,the thermo-oxidative aging property decreased as the proportion of PVC increased %K [环氧化天然橡胶 %K PVC %K 共混 %K 热氧降解 %K 环氧化天然橡胶 %K PVC %K 共混 %K 热氧降解 %K ENR %K PVC %K blend %K thermo-oxidative degradation] %U http://www.rubbertire.cn/gy/xjgy/ch/reader/view_abstract.aspx?file_no=XJ20010602&flag=1