%0 Journal Article %T 氯丁橡胶-黄铜粘合界面微量元素含量对 粘合力的影响 %A 万呈呈 %A 李利 %A 杨林彬 %A 谢添 %J - %D 2019 %R 10.12136/j.issn.1000-890X.2019.08.0573 %X 对填充不同炭黑品种氯丁橡胶(CR)(硫化胶)-黄铜粘合界面微量元素含量与粘合力的关系进行分析,研究老化前、热老化后和水浸泡后CR-黄铜粘合界面微量元素含量的变化,以及化学粘合和物理粘合时CR-黄铜粘合界面微量元素含量对粘合力的影响。结果表明:化学粘合时,热老化后CR-黄铜粘合界面的S元素质量分数、Cu元素质量分数和S元素/Cu元素质量分数比增大,粘合力增大;水浸泡后CR-黄铜粘合界面的S元素质量分数减小,Cu元素质量分数增大,粘合力减小;物理粘合时,热老化后和水浸泡后CR-黄铜粘合界面的微量元素质量分数变化不大,其微量元素质量分数不能表征粘合力大小。;The relationship between trace element content in the bonding interface of chloroprene rubber (CR)(vulcanizate) filled with different carbon black varieties-brass and adhesion was analyzed.The changes of trace element content in the CR-brass bonding interface before aging,after thermal aging and after water immersion were investigated,and the effects of trace element content in the CR-brass bonding interface by chemical bonding and physical bonding on adhesion were studied.The results showed that,after thermal aging,the S element mass fraction,Cu element mass fraction and S element/Cu element mass fraction ratio of CR-brass bonding interface by chemical bonding increased,and the adhesion increased.After water immersion,the S element mass fraction of CR-brass bonding interface by chemical bonding was decreased,the Cu element mass fraction increased,and the adhesion decreased.After thermal aging and water immersion,the trace elements mass fraction of CR-brass bonding interface by physical bonding had little change,and the trace elements mass fraction could not be used to characterize the adhesion strength %K [氯丁橡胶 %K 黄铜 %K 粘合界面 %K 微量元素 %K 粘合力 %K 化学粘合 %K 物理粘合 %K 氯丁橡胶 %K 黄铜 %K 粘合界面 %K 微量元素 %K 粘合力 %K 化学粘合 %K 物理粘合 %K CR %K brass %K bonding interface %K trace elements %K adhesion %K chemical bonding %K physical bonding] %U http://www.rubbertire.cn/gy/xjgy/ch/reader/view_abstract.aspx?file_no=XJ2018-0175&flag=1