%0 Journal Article
%T Quinolinium Dichromate Oxidation of Aliphatic Aldehydes: A Kinetic Study
%A Chaubey
%A Girija S.
%A Das
%A Simi
%A Mahanti
%A Mahendra K.
%J -
%D 2003
%X SaŁżetak Kinetic data on the rates of quinolinium dichromate oxidation of a series of aliphatic aldehydes have been determined and discussed with reference to aldehyde hydration equilibria. Kinetic results support a pathway proceeding via a rate-determining oxidative decomposition of a chromate ester of an aldehyde hydrate. A cyclic transition state is suggested; being a H¨ąckel-type system (4n + 2), this would be an allowed process. The deuterium isotope effect for the oxidation of acetaldehyde (kH / kD = 6.4) indicated a carbon-hydrogen cleavage rather than a carbon-carbon cleavage
%K kinetics
%K oxidation
%K aliphatic aldehydes
%K quinolinium dichromate
%K mechanism
%U https://hrcak.srce.hr/index.php?show=clanak&id_clanak_jezik=151759