%0 Journal Article
%T Ferrocene Compounds. XXXV. Reactions of 1,1'-Ferrocenylenebis(carbinyl acetate) and Derived Quaternary Iodide with Hydroxyalkanoates
%A Kova£¿
%A Veronika
%A Rapi£¿
%A Vladimir
%J -
%D 2003
%X Sa£¿etak Biscarbinol, 1,1'-Fn[CH(CH3)OH)]2 (1), and the corresponding bis(carbinyl acetate) 2 were prepared according to the described procedures. Amination of bisacetate 2 with Me2NH and subsequent quaternization of the intermediate amine 3 gave iodide 4. By the action of alkoxides derived from methyl glycolate and methyl lactate on acetate 2 or salt 4, unsaturated ether 5 (8¨C22 %), unsaturated esters 6a (6b) (2¨C18 %) and ester-ethers 7a (7b) (6¨C15 %) were obtained. The structure of heteroannularly substituted nonsymmetric ferrocene derivatives 5¨C7 was undoubtedly confirmed by elemental and spectroscopic analyses, and the reaction mechanisms of their formation were proposed
%K ¦Á
%K ¦Á'-(1
%K 1'-ferrocenylene)bisethanol
%K ¦Á
%K ¦Á'-(1
%K 1'-ferrocenylene)bis(ethyl
%K acetate) and derived quaternary iodide
%K methyl glycolate
%K methyl lactate
%U https://hrcak.srce.hr/index.php?show=clanak&id_clanak_jezik=151643