%0 Journal Article
%T Electroorganic synthesis of disulfonamide substituted p-benzoquinone by hydroquinone electrochemical oxidation
%A Bakeer
%A Deeb
%A Khadam
%A Waleed
%A Madwar
%A Rushdi
%A Nakhla
%A Abeer
%A Nassif
%A Seba
%J -
%D 2019
%R 10.5599/jese.555
%X Sa£żetak This study illustrates electrochemical behavior of hydroquinone and 4-amino-6-chlorobenzene-1,3-disulfonamide in the phosphate buffer solution evaluated by cyclic voltammetry. It was found that the peak of the hydroquinone oxidation potential in the presence of 4-amino-6-chlorobenzene-1,3-disulfonamide is shifted to more positive values compared to hydroquinone alone. Based on these results, the electrochemical synthesis of new disulfonamide substituted p-benzoquinone is proposed and carried out via electrochemical oxidation of hydroquinone in the presence of 4-amino-6-chlorobenzene-1,3-disulfonamide in the electrolytic cell. It has been concluded that hydroquinone is converted into disulfonamide substituted p-benzoquinone via an ECE mechanism. The successful electrochemical synthesis was conducted in the water/ethanol mixture under green conditions without any toxic reagents or solvents and with high atom economy
%K Cyclic voltammetry
%K electrochemical synthesis
%K hydroquinone
%K disulfonamide
%U https://hrcak.srce.hr/index.php?show=clanak&id_clanak_jezik=309849