%0 Journal Article
%T Dichlorophosphoranides Stabilized by Formamidinium Substituents
%A Hurieva
%A Anastasiya
%A Koidan
%A Georgyi
%A Kostyuk
%A Aleksandr
%A Marchenko
%A Anatoliy
%A Rozhenko
%A Alexander B.
%A Rusanov
%A Eduard
%J -
%D 2020
%R https://doi.org/10.1155/2020/9856235
%X Dichlorophosphoranides featuring N,N-dimethyl-N¡ä-arylformamidine substituents were isolated as individual compounds. Dichlorophosphoranide 9 was prepared by the multicomponent reaction of C-trimethylsilyl-N,N-dimethyl-N¡ä-phenylformamidine and N,N-dimethyl-N¡ä-phenylformamidine with phosphorus trichloride. Its molecular structure derived from a single-crystal X-ray diffraction was compared to the analogous dibromophosphoranide prepared previously by us by the reaction of phosphorus tribromide with N,N-dimethyl-N¡ä-phenylformamidine. It was shown that a chlorophosphine featuring two N,N-dimethyl-N¡ä-mesitylformamidine substituents reacted with hydrogen chloride to form dichlorophosphoranide 11. Its molecular structure was also determined by X-ray analysis and compared with that of closely related dichlorophosphoranide C
%U https://www.hindawi.com/journals/htrc/2020/9856235/