%0 Journal Article
%T Experimental Mixed-Gas Permeability, Sorption and Diffusion of CO2-CH4 Mixtures in 6FDA-mPDA Polyimide Membrane: Unveiling the Effect of Competitive Sorption on Permeability Selectivity
%J Membranes | An Open Access Journal from MDPI
%D 2019
%R https://doi.org/10.3390/membranes9010010
%X The nonideal behavior of polymeric membranes during separation of gas mixtures can be quantified via the solution-diffusion theory from experimental mixed-gas solubility and permeability coefficients. In this study, CO 2-CH 4 mixtures were sorbed at 35 ¡ãC in 4,4¡ä-(hexafluoroisopropylidene)diphthalic dianhydride (6FDA)-m-phenylenediamine (mPDA)¡ªa polyimide of remarkable performance. The existence of a linear trend for all data of mixed-gas CO 2 versus CH 4 solubility coefficients¡ªregardless of mixture concentration¡ªwas observed for 6FDA-mPDA and other polymeric films; the slope of this trend was identified as the ratio of gas solubilities at infinite dilution. The CO 2/CH 4 mixed-gas solubility selectivity of 6FDA-mPDA and previously reported polymers was higher than the equimolar pure-gas value and increased with pressure from the infinite dilution value. The analysis of CO 2-CH 4 mixed-gas concentration-averaged effective diffusion coefficients of equimolar feeds showed that CO 2 diffusivity was not affected by CH 4. Our data indicate that the decrease of CO 2/CH 4 mixed-gas diffusion, and permeability selectivity from the pure-gas values, resulted from an increase in the methane diffusion coefficient in mixtures. This effect was the result of an alteration of the size sieving properties of 6FDA-mPDA as a consequence of CO 2 presence in the 6FDA-mPDA film matrix. View Full-Tex
%U https://www.mdpi.com/2077-0375/9/1/10