%0 Journal Article
%T Synthesis of [email protected] Core¡ªShell Nanoparticles as Efficient Electrocatalyst for Methanol Electro-Oxidation
%J Nanomaterials | An Open Access Journal from MDPI
%D 2019
%R https://doi.org/10.3390/nano9111644
%X Bimetallic [email protected] nanoparticles (NPs) with Pt monolayer shell are of much interest for applications in heterogeneous catalysts because of enhanced catalytic activity and very low Pt-utilization. However, precisely controlled synthesis with uniform Pt-monolayers and stability on the AuNPs seeds remain elusive. Herein, we report the controlled deposition of Pt-monolayer onto uniform AuNPs seeds to obtain [email protected] core¨Cshell NPs and their Pt-coverage dependent electrocatalytic activity for methanol electro-oxidation. The atomic ratio between Au/Pt was effectively tuned by varying the precursor solution ratio in the reaction solution. The morphology and atomic structure of the [email protected] NPs were analyzed by high-resolution scanning transmission electron microcopy (HR-STEM) and X-ray diffraction (XRD) techniques. The results demonstrated that the [email protected] core¨Cshell NPs with Pt-shell thickness (atomic ratio 1:2) exhibit higher electrocatalytic activity for methanol electro-oxidation reaction, whereas higher and lower Pt ratios showed less overall catalytic performance. Such higher catalytic performance of [email protected] NPs (1:2) can be attributed to the weakened CO binding on the Pt/monolayers surface. Our present synthesis strategy and optimization of the catalytic activity of [email protected] core¨Cshell NPs catalysts provide promising approach to rationally design highly active catalysts with less Pt-usage for high performance electrocatalysts for applications in fuel cells. View Full-Tex
%U https://www.mdpi.com/2079-4991/9/11/1644