%0 Journal Article
%T Ag/AgCl@WO<sub>3</sub>/MIL-101可见光催化剂的合成及其光催化性能的研究<br>Preparation of Ag/AgCl@WO<sub>3</sub>/MIL-101 and Its Visible-Light Photocatalytic Performance
%A 苏聪超
%A 刘艳
%A 苗永霞
%A 刘建平
%A 杨新丽
%J Journal of Advances in Physical Chemistry
%P 13-22
%@ 2168-6130
%D 2020
%I Hans Publishing
%R 10.12677/JAPC.2020.92002
%X 采用微波辅助合成方法将WO<sub>3</sub>固载到金属有机骨架MIL-101(Cr)上，借助于沉积沉淀–光还原方法将Ag/AgCl和WO<sub>3</sub>/MIL-101复合在一起，制备出Ag/AgCl@WO<sub>3</sub>/MIL-101可见光催化剂。利用FT-IR、XRD、UV-Vis-DRS和XPS测试技术对该催化剂进行了表征。结果表明，Ag/AgCl和WO<sub>3</sub>的引入没有改变MIL-101的结构，催化剂在可见光区有强烈的光吸收。当WO<sub>3</sub>的负载量为0.3(w)%，Ag的负载量为3.4(w)%时，Ag/AgCl@WO<sub>3</sub>/MIL-101对70 mL 20 mg/L的罗丹明B溶液的降解率达到100%，并且该催化剂具有较好的稳定性。<br/>Tungsten oxide (WO<sub>3</sub>) was supported on MIL-101(Cr), affording a hybrid material WO<sub>3</sub>/MIL-101 by a microwave-assisted deposition method. Then, the plasmonic Ag/AgCl@WO<sub>3</sub>/MIL-101 catalyst was prepared by the deposition-precipitation-photoreduction method and characterized by FT-IR, XRD, UV-Vis-DRS and XPS techniques. It was found that the structure of MIL-101 was well preserved after the introduction of WO<sub>3</sub> and Ag/AgCl, which showed strong light absorption in the visible region. When the loadings of WO<sub>3</sub> and Ag was 0.3(w)% and 3.4(w)%, Ag/AgCl@WO<sub>3</sub>/MIL-101 exhibited a high photocatalytic activity and good stability for the degradation of RhB under visible light irradiation.
%K 金属有机骨架，Ag/AgCl，WO<sub>3</sub>，MIL-101，可见光，光催化剂<br>Metal Organic Framework
%K Ag/AgCl
%K WO<sub>3</sub>
%K MIL-101
%K Visible Light
%K Photocatalyst
%U http://www.hanspub.org/journal/PaperInformation.aspx?PaperID=36207