%0 Journal Article
%T Design and synthesis of high heat
%A Chanjuan Liu
%A Chun Wei
%A Hua Li
%A Xiaohua Huang
%J High Performance Polymers
%@ 1361-6412
%D 2019
%R 10.1177/0954008317749018
%X In this study, a novel diamine monomer, 4-(4-trifluoromethylthiophenyl)-2,6-bis(4-aminophenyl)pyridine (FTPAP) was synthesized through two-step reaction from 4-trifluoromethylthiobenzaldehyde and 4-nitroacetophenone as raw materials, and then the structure of FTPAP was characterized by Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance, and mass spectrometry. A series of fluorinated polyimides were prepared from FTPAP with five commercial dianhydrides, namely, pyromellitic dianhydride, biphenyl tetracarboxylic dianhydride, oxydiphtahalic anhydride, benzophenone tetracarboxylic dianhydride, and 4,4¡ä-(hexafluoroisopropylidene) diphthalic anhydride. The structure and performance of the fluorinated polymers were fully characterized by FTIR, differential scanning calorimetry, thermogravimetric analysis, and wide-angle X-ray diffraction (WAXD). The inherent viscosity of polymers ranged from 0.41 to 1.45 dL g£¿1. These polymers displayed good solubility in polar aprotic solvents, such as N,N-dimethylformamide, N,N-dimethylacetamide, dimethyl sulfoxide, and N-methyl-2-pyrrolidone, at room temperature or on heating. Furthermore, they exhibited outstanding thermal stability with glass transition temperatures beyond 305¡ãC, and the temperature of 10% weight loss was in the range of 514¨C573¡ãC with more than 56% residue at 800¡ãC under nitrogen. Moreover, they showed high optical transparency with the cutoff wavelengths in the range of 385¨C457 nm and excellent hydrophobic property with contact angle in the range of 82.8¨C97.6¡ã. In addition, the results of WAXD indicated that all of the polymers presented amorphous structure
%K Fluorinated polyimides
%K thermal stability
%K solubility
%K optical transparency
%K hydrophobicity
%U https://journals.sagepub.com/doi/full/10.1177/0954008317749018