%0 Journal Article
%T Formation of high
%A Gang Liu
%A Ming Zhong
%A Shouzhi Pu
%A Yongjun Liu
%J Progress in Rubber, Plastics and Recycling Technology
%@ 1478-2413
%D 2019
%R 10.1177/1477760619843536
%X Recycled poly(ethylene terephthalate) (R-PET)/high-density polyethylene (HDPE)/glycidyl methacrylate grafted poly(ethylene-octene) (mPOE) blends, in which the binary (HDPE/mPOE) dispersed phase was of a HDPE core-mPOE shell structure, were prepared. For this purpose, HDPE-g-mPOE graft copolymers were prepared in HDPE/mPOE blends via reactive extrusion with the presence of the free radical initiator dicumyl peroxide (DCP). Then, R-PET was blended with the HDPE/mPOE blends by melt extrusion. The effect of the DCP and mPOE content in the HDPE/mPOE blends on the phase morphology and mechanical properties of the R-PET/HDPE/mPOE blends were studied systematically. It was found that the blends containing reactive compatibilizer exhibited the encapsulation of the HDPE by the mPOE, forming core¨Cshell particles dispersed phase morphology. The graft chains of HDPE-g-mPOE-g-PET formed by the in situ reaction between R-PET and mPOE phases reduced the interfacial tension. Consequently, the dispersed phase morphology was observed to form smaller diameter core¨Cshell particles. The resultant blends exhibited an effect on both the thermal and mechanical properties. Differential scanning calorimetric analysis showed the dispersed phase particles could act as a nucleating agent in the R-PET matrix to improve the crystallization temperature, while the graft copolymers formed in the compatibilized R-PET/HDPE/mPOE blend decreased the nucleation activity. Notched Charpy impact strength and elongation at break of the R-PET were improved by forming the core¨Cshell particles dispersed phase morphology
%K Recycled poly(ethylene terephthalate)
%K core¨Cshell particles
%K properties
%U https://journals.sagepub.com/doi/full/10.1177/1477760619843536