%0 Journal Article
%T Achieving large electric-field-induced strain in lead-free piezoelectrics
%A Deborah Schneider
%A Haosu Luo
%A John E. Daniels
%A M¨¢rton Major
%A Patrick Tung
%A Richard Chen
%A Torsten Granzow
%J Materials Research Letters
%D 2019
%R https://doi.org/10.1080/21663831.2019.1570979
%X ABSTRACT Lead-free piezoelectric single crystals of Fe-doped 0.95(Bi1/2Na1/2)TiO3-0.05BaTiO3 are shown to combine multiple mechanisms for high strain and an effective piezoelectric coefficient of up to 3260£¿pm/V. This is explained based on the analysis of superstructure reflections from diffuse synchrotron x-ray scattering. It depends on three factors: (1) the stabilization of a local tetragonal structure by (Fe¡¯- VO£¿£¿)£¿ defect dipoles, (2) the reversible creation of a morphotropic phase boundary under field, and (3) the field-induced reversible transition between a short-range ordered relaxor and a long-range ordered ferroelectric state. GRAPHICAL ABSTRACT IMPACT STATEMENT The observation that a combination of three different physical mechanisms produces unprecedently high piezoelectric response in a lead-free piezoelectric presents a breakthrough in the fundamental understanding of optimizing piezoelectric properties
%U https://www.tandfonline.com/doi/full/10.1080/21663831.2019.1570979