%0 Journal Article
%T Phase stability and thermoelectric properties of semiconductor-like tetragonal FeAl2
%A Daisuke Nishio-Hamane
%A Hirotada Gotou
%A Kaoru Kimura
%A Kazuki Tobita
%A Koichi Kitahara
%A Naoki Sato
%A Yukari Katsura
%J Science and Technology of Advanced Materials
%D 2019
%R https://doi.org/10.1080/14686996.2019.1662272
%X ABSTRACT Tetragonal FeAl2 is a high-pressure phase and is predicted to exhibit semiconductor-like behavior. We investigated the pressure and temperature synthesizing conditions of tetragonal FeAl2, supported by in situ X-ray diffractions, using synchrotron radiation during heating the sample under a pressure of 20 GPa. Based on the determined optimal conditions, we synthesized the bulk polycrystalline samples of tetragonal FeAl2 at 7.5 GPa and 873 K, using a multi-anvil press and measured its thermoelectric properties. The Seebeck coefficient of tetragonal FeAl2 showed a large negative value of ¨C 105 ¦ÌV/K at 155 K and rapidly changed to a positive value of 75 ¦ÌV/K at 400 K. Although these values are the largest among those of Fe¨CAl alloys, the maximum power factor remained at 0.41 mW/mK2 because the carrier concentration was not tuned. A comparison of the Gibbs free energy of tetragonal FeAl2, triclinic FeAl2 and FeAl+Fe2Al5 revealed that tetragonal FeAl2 became unstable as the temperature increased, because of its smaller contribution of vibrational entropy. GRAPHICAL ABSTRAC
%U https://www.tandfonline.com/doi/full/10.1080/14686996.2019.1662272