%0 Journal Article
%T Thorium(IV) and Uranium(IV) Phosphaazaallenes
%J Inorganics | An Open Access Journal from MDPI
%D 2019
%R https://doi.org/10.3390/inorganics7090105
%X The synthesis of tetravalent thorium and uranium complexes with the phosphaazaallene moiety, [N( tBu)C=P(C 6H 5)] 2£¿, is described. The reaction of the bis(phosphido) complexes, (C 5Me 5) 2An[P(C 6H 5)(SiMe 3)] 2, An = Th, U, with two equivalents of tBuNC produces (C 5Me 5) 2An(CN tBu)[ ¦Ç 2-( N, C)-N( tBu)C=P(C 6H 5)] with concomitant formation of P(SiMe 3) 2(C 6H 5) via silyl migration. These complexes are characterized by NMR and IR spectroscopy, as well as structurally determined using X-ray crystallography. View Full-Tex
%U https://www.mdpi.com/2304-6740/7/9/105