%0 Journal Article
%T 廊坊市近地面臭氧及其前体物污染特征和相关性分析
The Change Feature of Surface O3 and Its Precursors Concentration and Their Relevance in Langfang
%A 李娜
%A 周涛
%A 李红星
%J Advances in Environmental Protection
%P 534-542
%@ 2164-5493
%D 2019
%I Hans Publishing
%R 10.12677/AEP.2019.94074
%X
利用2013年~2017年廊坊市5个环境监测站O3与NO2、NO、CO的逐时和日最大8 h滑动平均浓度连续观测资料,探讨廊坊市近地面臭氧和前体物的污染特征以及两者间相关关系。研究发现,廊坊市主城区内的监测站臭氧浓度值高于非主城区;臭氧日变化特征呈现“单峰型”,早上7:00左右浓度最低,下午16:00左右浓度最高;并且臭氧浓度日峰值出现的时间和大小具有季节差异;臭氧浓度具有夏季最高,冬季最低的季节变化特征;同时发现研究时段内臭氧浓度随时间呈上升趋势;NO2、NO、CO等前体物的日变化曲线与臭氧相反,呈“双峰型”,早晨峰值出现的时间和早高峰吻合,夜间峰值位于晚高峰之后;前体物浓度的季节变化均是冬季 > 秋季 > 春季 > 夏季,NO2、NO、CO与O3为负相关关系,相关系数分别为?0.701、?0.698和?0.503。
According to the sequential hourly data on O3 and NO2, NO, CO of 5 environmental observations during 2013 to 2017 in Langfang, the change feature of surface O3 and its precursors’ concentration and their relevance had been analyzed. The results showed that: the O3 concentration of urban environmental observations was higher than suburban stations. The diurnal variation of O3 was distributed in unimodal pattern and the minimum appeared at 7:00, the maximum appeared at 16:00. There were seasonal differences in occurrence time and O3 daily peak value, the seasonal change of O3 concentration was summer > spring > autumn > winter. In addition, the O3 concen-tration increased with time during the study period. The daily variation curves of precursors such as NO2, NO, and CO had a bimodal distribution and were opposite to O3, the peak of morning coin-cided with the traffic morning rush hour, the night peak lagged behind the evening rush hour. The seasonal changes of the precursors concentration were same as winter > autumn > spring > sum-mer. NO2, NO, CO and O3 were negatively correlated and the correlation coefficients were ?0.701, ?0.698 and ?0.503, respectively.