%0 Journal Article
%T One-Pot Process of Naphthoquinones Synthesis from Hydroquinone in the Presence of Solutions of Mo-V-P Heteropolyacids as Bifunctional Catalysts
%A Leonid L. Gogin
%A Elena G. Zhizhina
%A Zinaida P. Pai
%J Modern Research in Catalysis
%P 1-9
%@ 2168-4499
%D 2019
%I Scientific Research Publishing
%R 10.4236/mrc.2019.81001
%X 1,4-Naphthoquinones (NQ) is a class of organic compounds with a number of
important properties. However, the existing methods of their synthesis either give a low NQ
yield or multistage and require a lot of time. In the present work new one-pot process of NQ synthesis from hydroquinone (HQ)
and substituted 1,3-dienes at room temperature is proposed. The solution of
heteropolyacid H7PMo8V4O40 (HPA-4) is
used as a bifunctional (acid and redox) catalyst for this process. The influence of
a number of factors on key process parameters has been studied. It is
demonstrated that unsubstituted and a number of alkyl substituted
NQ with the yields of 50% - 80% and purity of 92%