%0 Journal Article %T CoFe2与CoFe2O4质量比及MgO稀释对CoFe2@CoFe2O4磁性的影响<br>Effects of mass ratio of CoFe2 to CoFe2O4 and the dilution by MgO on the magnetic properties of CoFe2@CoFe2O4 %A 马永青 %A 刘畅 %A 王敏 %J 复合材料学报 %D 2018 %R 10.13801/j.cnki.fhclxb.20170609.003 %X 采用金属有机盐热分解方法制备了MgO包覆的CoFe2O4纳米粒子(CoFe2O4@MgO),然后将CoFe2O4@MgO在H2中还原,接着在空气中氧化制备了一组CoFe2@CoFe2O4@MgO样品;用盐酸溶液溶解CoFe2@CoFe2O4@MgO中的MgO获得另一组样品(CoFe2@CoF2O4)。测量并绘制了CoFe2@CoFe2O4@MgO和CoFe2@CoF2O4的磁化强度随外磁场及温度变化的关系曲线。随着氧化温度升高,CoFe2@CoFe2O4@MgO和CoFe2@CoF2O4的矫顽力Hc、饱和磁化强度Ms、剩磁比Mr/Ms及磁有序状态发生显著变化,这些变化强烈依赖于磁性粒子的各向异性及粒子间的偶极相互作用。 MgO coated CoFe2O4 nanoparticles (CoFe2O4@MgO) were synthesized by the thermal decomposition of a metal-organic salt. CoFe2O4@MgO was reduced in H2 and then oxidized in air to prepare a group of CoFe2@CoFe2O4@MgO samples. Then MgO was dissolved by the HCl solution to obtain the other group of samples (CoFe2@CoF2O4). The magnetic field and temperature dependent magnetization curves were measured on CoFe2@CoF2O4 and CoFe2@CoFe2O4@MgO samples. The significant changes of coercivity Hc, saturation magnetization Ms and remanence ratio Mr/Ms as well as the magnetic ordering states with the oxidation temperature are observed for CoFe2@CoF2O4 and CoFe2@CoFe2O4@MgO samples, which strongly depend on the anisotropy of the magnetic particles and interparticle dipolar interaction. 国家自然科学基金(51471001) %K CoFe2@CoFe2O4 %K 复合磁体 %K 磁性材料 %K 磁性质 %K 各向异性 %K 偶极相互作用< %K br> %K CoFe2@CoFe2O4 %K composite magnets %K magnetic materials %K magnetic properties %K anisotropy %K dipolar interaction %U http://fhclxb.buaa.edu.cn/CN/abstract/abstract14004.shtml