%0 Journal Article %T 阻抗渐变低介电BaTiO3/PVDF复合纤维膜的设计与电纺制备<br>Design and fabrication of low-dielectric BaTiO3/PVDF composite fibrous mat with impedance gradient by electrospinning %A 吴再辉 %A 秦珊 %A 白帆 %A 吴俊涛 %J 复合材料学报 %D 2016 %R 10.13801/j.cnki.fhclxb.20151027.002 %X 阻抗渐变材料在医用可穿戴设备中起着重要作用。为了实现不同材料之间的相互匹配特性,低介电阻抗渐变材料的研究尤为重要。利用静电纺丝的方法,设计制备了具有阻抗渐变性的低介电钛酸钡(BaTiO3)/聚偏氟乙烯(PVDF)复合纤维膜。结果表明:BaTiO3纳米粒子可在纤维网络中均匀分布,通过调节其质量分数,能够有效调节BaTiO3/PVDF复合纤维膜的介电常数在1~7的范围内,BaTiO3/PVDF复合纤维膜对不同的电场频率具有不敏感性。BaTiO3/PVDF复合纤维膜还具有良好的力学性能,能够有效满足可穿戴设备的材料需求。 Impedance gradient materials have played an important role in the medical wearable devices. For realizing the matching character between different materials, the research about low-dielectric materials with impedance gradient is particularly important. By means of the electrospinning, low-dielectric barium titanate (BaTiO3)/polyvinylidene-fluoride (PVDF) composite fibrous mat with impedance gradient was designed and prepared. The results show that the BaTiO3 nano-particles can distribute in the fiber uniformly. By adjusting the mass fraction of nano-particles, the dielectric constant of BaTiO3/PVDF composite fibrous mat can arrange from 1 to 7, and it is also insensible to the different frequencies of electric field. BaTiO3/PVDF composite fibrous mat possesses good mechanical property and can meet the requirements of the wearable device materials. 国家国际科技合作专项(2013DFA31770);国家自然科学基金(51373007,51003004);国家“973”计划(2010CB934700);北京市自然科学基金(2142019) %K 低介电 %K 静电纺丝 %K 聚偏氟乙烯 %K 钛酸钡 %K 复合材料< %K br> %K low-dielectric %K electrospinning %K polyvinylidene-fluoride %K BaTiO3 %K composite %U http://fhclxb.buaa.edu.cn/CN/abstract/abstract13342.shtml